2008

Publications from 2008

Title The role of an insulating surface layer on the relaxation time of the ionic redistribution in an electrolytic cell

Author(s) Freire, FCM; Barbero, G; Scalerandi, M; Alexe-Ionescu, AL
Source MOLECULAR CRYSTALS AND LIQUID CRYSTALS 48093-102 2008
Conference Title 21st International Liquid Crystal Conference
Conference Date JUL 02-07, 2006
Conference Location Keystone, CO
Abstract We analyze the influence of a surface dielectric layer on the transient phenomena related to the ionic redistribution in an electrolytic cell submitted to a step-like external voltage. The adsorption-desorption phenomenon is taken into account in the famework of the Gouy-Chapman approximation, where the ions are assumed dimensionless. In the limit of small amplitude of the applied voltage, where the equations of the problem can be linearized, we obtain an analytical solution for the surface densities of ions, for the electrical potential and for the relaxation time for the transient phenomena. In the general case, when the linearized analysis is no longer valid, the solution of the problem is obtained numerically. The role of the thickness of the dielectric layer on the relaxation time is also discussed.
ISSN 1542-1406
DOI 10.1080/15421400701825656

Title Dye adsorption alteration of anchoring properties of planar orienting films
Author(s) Dascalu, C; Uncheselu, C; Eseanu, N; Alexe-Ionescu, AL
Source JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS 10 (2):363-368 2008
Conference Title 8th International Balkan Workshop on Applied Physics
Conference Date JUL 05-07, 2007
Conference Location Constanta, ROMANIA
Abstract Planar orienting polymeric films proved to have strong anchoring properties for nematic liquid crystals. Inserting a small quantity of azo-dye in a nematic liquid crystal 5CB changes the anchoring properties due to specific adsorption mechanisms. Measurements have been performed choosing several dye concentrations, cell thicknesses and different dyes. Anchoring strength dependence on the cell thickness has been investigated.
ISSN 1454-4164

Title Anchoring of nematic liquid crystals on a thin polymeric film
Author(s) Alexe-Ionescu, AL; Barbero, G; Komitov, L
Source PHYSICAL REVIEW E 77 (5): Art No. 051701 2008
Abstract We analyze the influence of a thin polymer layer with lateral side groups on the anchoring of a nematic liquid crystal. We show that the effective anisotropic part of the anchoring energy depends on the coupling of the nematic with the polymer side groups, as well as on the coupling of the polymer side groups with the surface. The relaxation time for the nematic orientation induced by an external field is evaluated by considering the surface dissipation connected to the relative motion of the nematic director with respect to the polymer side groups.
ISSN 1539-3755
DOI 10.1103/PhysRevE.77.051701

Title Current measurements across a nematic cell submitted to an external voltage and its equivalent electrical circuit
Author(s) Atasiei, R; Alexe-Ionescu, AL; Dias, JC; Evangelista, LR; Barbero, G
Source CHEMICAL PHYSICS LETTERS 461 (1-3):164-169 2008
Abstract The dielectric characterization of a liquid crystal by means of measurements of electric current. owing in the circuit is discussed. Few equivalent circuits are analyzed focusing the attention on the role of the resistance over which the potential drop is measured to determine the total current in the circuit. A comparison of our model with experimental data is presented, showing that the model works well when the maximum applied voltage is below the threshold voltage for Freedericksz’s transition. In this case, the description of the nematic cell using a Maxwell-Wagner model is possible. (c) 2008 Elsevier B. V. All rights reserved.
ISSN 0009-2614
DOI 10.1016/j.cplett.2008.06.089

Title Reorientation effect on the current-voltage characteristics of a nematic cell
Author(s) Atasiei, R; Alexe-Ionescu, AL; Dascalu, C; Dias, JC; de Souza, RT
Source PHYSICS LETTERS A 372 (39):6116-6120 2008
Abstract Possible mechanisms explaining the character of the relation I = I(V) for a nematic cell subjected to a large electric field are discussed, taking into account the reorientation effect of the nematic director induced by the external electric field. The analysis is performed in the quasi-static regime where the nematic orientation follows the time variation of the external field without delay. The time variation of the equivalent capacitance of the cell is equivalent to a pure resistance, and is responsible for a current peak when the applied voltage overcomes the threshold voltage for the transition of Freedericksz. (c) 2008 Published by Elsevier B.V.
ISSN 0375-9601
DOI 10.1016/j.physleta.2008.08.006

Title IONIC CONTRIBUTIONS TO NEMATIC LIQUID CRYSTAL – CONDUCTING POLYMER INTERFACE PHENOMENA
Author(s) Atasiei, R; Dascalu, C; Eseanu, N; Raicopol, M; Alexe-Ionescu, AL
Source UNIVERSITY POLITEHNICA OF BUCHAREST SCIENTIFIC BULLETIN-SERIES A-APPLIED MATHEMATICS AND PHYSICS 70 (4):83-88 2008
Abstract The current to voltage response of a nematic liquid crystal (NLC) sample aligned with a conducting polymer has been measured A deviation from the linear behaviour of the current has been observed for long enough periods of triangular applied voltages. This is connected to the electric charge accumulation at nematic-polymer interface due to the asymmetric carrier injection and to redox phenomena for larger external fields. Our analysis has been carried out in a quasi-static regime in which the nematic director follows the time variation of the applied field without delay.
ISSN 1223-7027


Title Investigation on photonic-corral-mode quantum ring lasers by laser scanning microscopy
Author(s) Stanciu, GA; Stanciu, SG; Hristu, R; Kwon, O; Kim, DK
Editor(s) Marciniak, M
Source ICTON 2008: PROCEEDINGS OF 2008 10TH ANNIVERSARY INTERNATIONAL CONFERENCE ON TRANSPARENT OPTICAL NETWORKS, VOL 440-42 2008
Conference Title 10th International Conference on Transparent Optical Networks
Conference Date JUN 22-26, 2008
Conference Location Athens, GREECE
Abstract Ultra low threshold microcavity lasers are ideal candidates for high-density optical interconnect light Sources. Although they have been extensively studied for the last decade, mu A-level electro-pumped quantum confined lasers are still under investigation. Photonic-corral-mode quantum ring (PQR) lasers with the linewidth narrower than 0.55 angstrom generate micro-to-nano-ampere thresholds, and become ideal for CMOS-driven high-density emitter arrays for intra-chip optical interconnect as well as other applications such as displays. The PQR offers the following, advantages for extremely high-density emitter Source chip, over other semiconductor lasers presently available: a photonic quantum corral effect leads to naturally-born quantum wire behaviours for imminently recombinant carriers-, the mu A – nA threshold current capabilities mean kilo to mega PQR chip; root T – dependent spectral red shifts are smaller at high operating temperatures, allowing uniform and reliable chip emission with minimal temperature sensitivities. By using laser beam induced Current technique (LBIC) technique in laser scanning microscopy (LSM) we investigated the photocurrent confinement in the laser structure. The photocurrent map gives the possibility to analyze the laser structure Uniformity.


Title Photonic-Corral-Mode Quantum Ring Lasers investigated by Laser Scanning Microscopy and Near Field Microscopy
Author(s) Stanciu, GA; Stanciu, SG; Hristu, R; Kim, DK; Kwon, O
Source 2008 2ND ICTON MEDITERRANEAN WINTER (ICTON-MW)207-210 2008
Conference Title 2008 2nd ICTON Mediterranean Winter Conference
Conference Date DEC 11-13, 2008
Conference Location Marrakech, MOROCCO
Abstract Ultralow threshold microcavity lasers are ideal candidates for high-density optical interconnect light sources. Although they have been extensively studied for the last decade, mu A-level electro-pumped quantum confined lasers are still under investigation. Photonic-corral-mode quantum ring (PQR) lasers with the linewidth narrower than 0.55 angstrom generate micro-to-nano-ampere thresholds, and become ideal for CMOS-driven high-density emitter arrays for intra-chip optical interconnect as well as other applications such as displays. By using laser beam induced current technique (LBIC) technique in laser scanning microscopy (LSM) we investigated the photocurrent confinement in the laser structure. The photocurrent map gives the possibility to analyze the laser structure uniformity. The emission spectra of a PQR laser was investigated by using of microscopic optical fiber probe.


Title TUNNELING AT EMITTER PERIPHERY IN SILICON NITRIDE PASSIVATED InP/InGaAs HBTs
Author(s) Sachelarie, D; Predusca, G; Stanciu, GA; Stanciu, SG
Source 2008 IEEE 20TH INTERNATIONAL CONFERENCE ON INDIUM PHOSPHIDE AND RELATED MATERIALS (IPRM)391-394 2008
Conference Title 20th International Conference on Indium Phosphide and Related Materials
Conference Date MAY 25-29, 2008
Conference Location Versailles, FRANCE
Abstract This work presents a new explanation of the abnormal injection phenomena at emitter-base junction of the silicon nitride passivated InP-based heterojunction bipolar transistors. We have suggested that the emitter mesa sidewall is accumulated and that thermionic field emission from this zone becomes the principal component of the collector current. The proposed theoretical model is in good agreement with experimental collector current Gummel plots and with atomic force microscopy measurements of mesa emitter edge.
ISSN 1092-8669

Title AFM examination of sol-gel matrices doped with photo sensitizers
Author(s) Wysocka, K; Ulatowska-Jarza, A; Bauer, J; Holowacz, I; Savu, B; Stanciu, G; Podbielska, H
Source OPTICA APPLICATA 38 (1):127-136 2008
Abstract Various compounds may be entrapped into the sol-gel materials, including the photosensitive agents. The nanostructure of the final material depends on the matrix itself, as well as on the structural properties of doped compound. In this work, sol-gel matrices were produced from silica based precursor tetraethoxysilan (TEOS) in the form of single layers deposited on microscopic glasses. Materials were produced with molar ratios R = 20, 32, 40 (R – the number of solvent (ethanol) moles to the number of precursor (TEOS) moles). Additionally, for each material two various concentrations of photosensitizers were prepared (0.5 mg/ml and 0.05 mg/ml). On the basis of AFM images from Atomic Force Microscope Quesant 350, the following roughness parameters were evaluated: roughness average, peak-peak height, surface skewness and fractal dimension. The roughness average S-a parameter gives information about the statistical average properties. The peak-peak height S-y is defined as the height difference between the highest and the lowest pixel in the image. The surface skewness S-sk describes the asymmetry of the height distribution histogram. The fractal dimension S-fd is calculated for the different angles by analyzing the Fourier amplitude spectrum. Comparing the results we stated that average roughness increases with increasing R factor for protoporphyrine IX dimethylester (PPIX) (dimethyl-8,13-divinyl-3,7,12,17-tetramethyl-21H,23H-porphine-2,18-dipropionate) and photolon (18-carboxy-20-(carboxymethyl)-8-ethenyl-13-ethyl-2,3-dihydro3,7,12,17-tetramethyl-21H,23H-porphin-2-propionic acid) in higher concentrations. This means that photosensitizers used as dopants influence the smoothness of sol-gel matrix. We also noticed that the smallest roughness is observed in the material doped with PPIX in higher concentration. This was stated for all the images analyzed. This indicates that sol-gel matrix enclosures the PPIX molecules, resulting in smooth material.
ISSN 0078-5466

Title Nanostructured bioglass thin films synthesized by pulsed laser deposition: CSLM, FTIR investigations and in vitro biotests
Author(s) Floroian, L; Savu, B; Stanciu, G; Popescu, AC; Sima, F; Mihailescu, IN; Mustata, R; Sima, LE; Petrescu, M; Tanaskovic, D; Janackovic, D
Source APPLIED SURFACE SCIENCE 255 (5):3056-3062 2008
Abstract We report the synthesis by pulsed laser deposition of thin structures of two bioactive glasses belonging to the SiO2-Na2O-K2O-CaO-MgO-P2O5 system, on medical grade Ti substrates. We evaluated their biocompatibility after immersion in simulated body fluids and by performing cells adhesion tests. The Films were characterized by confocal scanning laser microscopy and Fourier transform infrared spectrometry, before and after 30 and 46 days immersion in fluids. Our studies demonstrated that deposited coatings were degraded in simulated fluids. A new apatite layer was synthesized by ions changing with the fluid during the decomposition of bioglasses. We investigated after immersion in fluids cells adhesion and the cytoskelet organization of synthesized structures, by fluorescence microscopy. A good adhesion to bioglass coatings was evidenced. (C) 2008 Elsevier B.V. All rights reserved.
ISSN 0169-4332
DOI 10.1016/j.apsusc.2008.08.105
Title Density of impurity states of shallow donors in a quantum well under intense laser field
Author(s) Niculescu, EC; Burileanu, LM; Radu, A
Source SUPERLATTICES AND MICROSTRUCTURES 44 (2):173-182 2008
Abstract The density of donor impurity states in a square GaAs-AlGaAs quantum well under an intense laser field is calculated taking into account the laser dressing effects on both the Coulomb potential and the confining potential. Using the effective-mass approximation within a variational scheme, the donor binding energy is obtained as a function of the laser dressing parameter, and the impurity position. Our results point out that a proper consideration of the density of impurity states may be of relevance in the interpretation of the optical phenomena related to shallow impurities in quantum wells, where the effects of an intense laser field compete with the quantum confinement. (C) 2008 Elsevier Ltd. All rights reserved.
ISSN 0749-6036
DOI 10.1016/j.spmi.2008.03.005


Title INTENSE FIELD EFFECTS ON HYDROGENIC IMPURITIES IN QUANTUM WELLS
Author(s) Niculescu, EC; Burileanu, LM; Radu, A
Source UNIVERSITY POLITEHNICA OF BUCHAREST SCIENTIFIC BULLETIN-SERIES A-APPLIED MATHEMATICS AND PHYSICS 70 (4):21-24 2008
Abstract In this paper we discuss the effect of the high-frequency laser field and the impurity position on the binding energy of the shallow acceptors in GaAs/Al0.3Ga0.7As quantum wells. The calculations were performed within the effective-mass approximation and by using a variational method.
ISSN 1223-7027


Title BINDING ENERGY OF A SCREENED DONOR IN A CYLINDRICAL QUANTUM WIRE UNDER APPLIED MAGNETIC FIELDS
Author(s) Niculescu, EC; Burileanu, L
Source UNIVERSITY POLITEHNICA OF BUCHAREST SCIENTIFIC BULLETIN-SERIES A-APPLIED MATHEMATICS AND PHYSICS 70 (2):55-62 2008
Abstract By a variational method, we calculate the binding energy of a screened hydrogenic donor in a GaAs-Al0 3Ga0 -As quantum-well wire in the presence of a uniform magnetic field applied parallel to the wire axis The binding energy is obtained as a function of the wire radius, the field strength and the screening parameter. Our results show that the effects of spatial variation of dielectric screening on edge wire donors are larger than those on center donors.
ISSN 1223-7027


Title BINDING ENERGY OF AN OFF-CENTER DONOR IN CYLINDRICAL QUANTUM-WELL WIRES UNDER INTENSE LASER FIELDS
Author(s) Niculescu, EC; Radu, A
Source UNIVERSITY POLITEHNICA OF BUCHAREST SCIENTIFIC BULLETIN-SERIES A-APPLIED MATHEMATICS AND PHYSICS 70 (1):67-75 2008
Abstract In this work, we have investigated the effect of the intense high frequency laser field on the ground-state binding energy of hydrogenic impurity in cylindrical GaAs-AlGaAs quantum well wires as function of the impurity position. The binding energies were obtained using the effective-mass approximation within a variational scheme. We have shown that in the strong confinement regime the presence of the linearly polarized laser radiation partially resolves the degeneracy of donor states corresponding to symmetrical position of the impurity.
ISSN 1223-7027




Title Preparation and characterization of new biocompatibilized polymeric materials for medical use
Author(s) Moldovan, L; Craciunescu, O; Zarnescu, O; Macocinschi, D; Bojin, D
Source JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS 10 (4):942-947 2008
Conference Title 5th International Conference on New Research Trends in Materials Science
Conference Date SEP, 2007
Conference Location Sibiu, ROMANIA
Abstract The aim of this study was to prepare 4 new composite biomaterials based on polyurethane (PU) blended with different mixtures of collagen (COL), elastin (EL) and glycosaminoglycans (GAG). Bioactivated polymeric materials were structurally characterized by light and electron microscopy and their biodegradability and in vitro biocompatibility were comparatively assessed. The biomaterials presented smooth surfaces and the porosity decreased when natural polymers were added. All polymeric blend variants allowed cell proliferation and adhesion, with a more extensive growth on PU-COL variant. In conclusion, it was demonstrated that these new composite materials were biocompatible and good candidates for medical device fabrication.
ISSN 1454-4164


Title Biomimetic hybrid inorganic/organic coatings in the increasing of the integration capacity of TiAlVZr bioalloy
Author(s) Proudana, M; Bojin, D; Ionita, D; Popa, M; Vasilescu, E; Drob, P
Source MOLECULAR CRYSTALS AND LIQUID CRYSTALS 4861175-1181 2008
Conference Title 9th International Conference on Frontiers of Polymers and Advanced Materials
Conference Date JUL 08-12, 2007
Conference Location Cracow, POLAND
Abstract This paper will address key issues related to the synthesis, characterization and utilization of inorganic/organic hybrid coatings on TiAlVZr bioalloy to control adsorption at interface and the integration capacity of the implant. To enhance the integration capacity function of the biomaterial is necessary to control the composition and structure via the use of hybrid materials consisting of organic and inorganic biomimetic phases [1,2]. Such composite coatings mimic the structure of natural materials of tissues, in our case hydroxyapatite (HA) by association of bovine serum albumin (BSA) with calcium phosphates matrices. Calcium phosphate coating have been deposited on metal substrates by electrochemical method.
ISSN 1542-1406
DOI 10.1080/15421400801917890


Title Characterization of the products and by-products obtained in the electrolytic refining of copper using scraps
Author(s) Buzatu, M; Moldovan, P; Bojin, D; Butu, M; Juhasz, I; Pop, E
Source REVISTA DE CHIMIE 59 (6):664-668 2008
Abstract Experimental data from electrolytic refining of copper anodes obtained from scraps are presented in this paper. Alloying elements behaviour from the secondary copper was studied by SEM microscopy, EDAX chemical characterization, and atomic emission spectroscopy.
ISSN 0034-7752


Title Characterization of the microstructure of the AA8006 alloy sheets and foils
Author(s) Stanica, C; Moldovan, P; Dobra, G; Bojin, D; Stanescu, C
Editor(s) DeYoung, DH
Source LIGHT METALS 2008703-707 2008
Conference Title Technical Session on Light Metals 2008 held at the 137th TMS Annual Meeting
Conference Date MAR 09-13, 2008
Conference Location New Orleans, LA
Abstract The paper presents the evolution of the AA8006 alloy microstructure in the rolling process in order to obtain sheets and foils. The paper’s purpose is to set the causes for the defect appearance in slabs, sheets and foils. The experiments put in evidence the role of the presence of iron, manganese and silicon compounds in the AA8006 alloy structure, in the casting and rolling processes. The role of the homogenization treatment was established by TEM examination of microstructure of the foils. The techniques of optical quantitative microscopy, electronic microscopy (SEM/EDS, TEM and JXA micro analyzer) were used for determining the m icrostructure of the alloy (slab, sheets and foils).
ISSN 0147-0809


Title Status of an R&D project of a positron gun at “Horia Hulubei” NIPNE Bucharest
Author(s) Vasilescu, A; Craciun, L; Ghita, IA; Constantinescu, O; Constantin, F; Chiojdeanu, C; Zoita, CN; Kiss, A; Bojin, D; Racolta, PM
Source APPLIED SURFACE SCIENCE 255 (1):46-49 2008
Conference Title 11th Workshop on Slow Position Beam Techniques for Solids and Surfaces
Conference Date JUL 09-13, 2007
Conference Location Musee Sci Naturelles, Orleans, FRANCE
Abstract A new positron gun (PG) will enable high sensitivity measurements in applications of positron annihilation spectroscopy in Romania. Some data concerning the design of a modular system for focussing, transport and acceleration of mono-energetic positrons in the range 0.8-50 keV have been obtained and experimenting on moderators and CDBS was performed. We present a short overview of the present status of the project and preliminary results from Coincidence Doppler Broadening Spectroscopy with a (NaCl)-Na-22 source, on Al samples. The entire positron gun system will be designed as a high-vacuum dedicated extension operating with two options: a 50 mCi (NaCl)-Na-22 source and in-line with the NIPNE cyclotron or a new intense compact cyclotron. (C) 2008 Elsevier B.V. All rights reserved.
ISSN 0169-4332
DOI 10.1016/j.apsusc.2008.05.193


Title Current-voltage characteristics of a nematic cell oriented by a doped polypyrrole surface layer
Author(s) Eseanu, N; Dascalu, C; Atasiei, R; Raicopol, M
Source PHYSICS LETTERS A 372 (14):2459-2463 2008
Abstract The influence of a surface layer of polypyrrole on the electrical response of a nematic cell is investigated. By assuming that the nematic sample can be described by means of a Maxwell-Wagner model, we determine the electrical conductivity and the dielectric constant of the surface layer and of the liquid crystal. From the experimental data, relevant to measurements performed on the sample submitted to an external excitation with zero average value and different amplitudes, we deduce information on the density of ions in the liquid crystal. The obtained values for the electrical conductivity, the dielectric constant and the ionic density of the two media are independent of the amplitude of the external voltage and of the same order of the ones measured by other groups. From this result we infer that a description in terms of Maxwell-Wagner model for linear media. represents a good approximation of our system. (c) 2007 Elsevier B.V. All rights reserved.
ISSN 0375-9601
DOI 10.1016/j.physleta.2007.11.038


Title High-power TEM00 composite solid-state laser with a short, telescopic resonator
Author(s) Dascalu, C
Source JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS 10 (6):1530-1533 2008
Abstract A short, telescopic laser resonator design is proposed for high-power, single-transverse mode emission from a lens shape composite solid-state laser. Such a laser combines the simplicity of the edge-pumped thin disk laser with the great advantage of axial heat flow in a very thin, below 50 mu m, active media thickness. The efficiency, output power and conditions of the single transverse mode oscillation are analyzed. For a device of a few millimeters wide, the slope efficiency of 49% and the threshold of a few wafts are predicted. The possibility of output power of kW level is analyzed.
ISSN 1454-4164